Surface-mediated selective photocatalytic aerobic oxidation reactions on TiO2 nanofibres
نویسندگان
چکیده
منابع مشابه
Green photocatalytic organic transformations by polyoxometalates vs. mesoporous TiO2 nanoparticles: selective aerobic oxidation of alcohols.
In this study, the catalytic activity of decatungstate (W10O32(4-)) supported on mesoporous TiO2 nanoparticle assemblies (DT-MTA) was compared with that of homogeneous [Bu4N]4W10O32 catalysts under mild conditions. Our experiments showed that both catalytic systems achieve exceptionally high activity and selectivity under UV-visible light oxidation of various para-substituted aryl alcohols, usi...
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Carbon nanofibres of the fishbone and parallel type were surface-oxidised by several methods. The untreated and oxidised fibres were studied with infrared spectroscopy, thermogravimetric analysis and XPS. Oxidation in a mixture of concentrated nitric and sulfuric acid turned out to be the most effective method for creating oxygen-containing surface groups. This treatment results not only in the...
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Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obtained.
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The photocatalytic oxidation of acetone vapor on TiO2/ZrO2 thin films is presented in this study. Acetone conversion data collected using a non-circulating tubular reactor are analyzed using a general power law model and a Langmuir–Hinshelwood– Hougen–Watson (LHHW) model; the LHHW model provides a slightly better fit than the 1/2 order power law model. The effects of reaction temperature and re...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2015
ISSN: 2046-2069
DOI: 10.1039/c5ra07518a